MMSL 2001, 70(S1):38-40

QUATERNARY KETOXIMES - NEW PERSPECTIVE COMPOUNDS FOR HYDROLYSIS OF TOXIC ORGANOPHOSPHATES

Radek Cibulka, František Hampl, Hana Kotoučová, Ondřej Páv, Alexandra Šilhánková, František Liška
Institute of Chemical Technology, Prague

Micellar systems made of amphiphilic quaternary pyridinium and quinolinium ketoximes readily hydrolyze 4-nitrophenyl diphenyl phosphate. and/or 1-(1-naphtylazo)napht-2-yl diphenyl phosphate, simulants of toxic organophosphates. Reactivity of these functional surfactants towards phosphates depends strongly on the position of their nucleophilic oxime function relative to micellar surface.

Keywords: Micelles; Pyridinium salts; Quinolinium salts; Ketoximes; Phosphates; Hydrolysis; Kinetics

Published: December 2, 2001  Show citation

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Cibulka, R., Hampl, F., Kotoučová, H., Páv, O., Šilhánková, A., & Liška, F. (2001). QUATERNARY KETOXIMES - NEW PERSPECTIVE COMPOUNDS FOR HYDROLYSIS OF TOXIC ORGANOPHOSPHATES. Vojenské Zdravotnické Listy, 70(Suppl.1), 38-40
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